595 | One Piece Episode

: Before falling unconscious, Zoro managed to cut away a field of ice spikes that the brothers intended to drop them onto, effectively saving the group.

: Caesar explains that Smiley is actually the toxic gas from the massive explosion that occurred on Punk Hazard four years ago.

: Law and Chopper use Law’s "Room" ability to teleport toward the back of the lab. Law instructs Chopper to investigate the drugs while Law focuses on finding a way to remove Caesar and Monet.

"Capture Master - The Pirate Alliance's Operation Begins!" (Episode 595) aired on , marking a pivotal shift in the Punk Hazard Arc as the newly formed alliance between Luffy and Law officially swings into action.

: This episode is part of the transition period for the opening theme. While "Hands Up!" became the new theme for Season 16, Funimation's original simulcast often omitted it due to licensing issues that were later resolved.

Within the laboratory, Caesar Clown reveals the dark history of (also known as Slime).